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Clorox Automatic Toilet Bowl Cleaner1-01/05/2015
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaClorox Automatic Toilet Bowl Cleaner1 is an easy-to-use tablet that continuously cleans and deodorizes toilet bowls with the power of Clorox Bleach.
Purpose of product.
Usage: Toilet bowl cleaner and disinfectant.Structure such as solid, liquid, aerosol etc.
Form: solidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20241221 Broadway
Oakland CA 94612
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)1-Bromo-3-chloro-5,5-dimethylhydantoin 016079-88-2 40.0-60.0 No 1,3-Dichloro-5,5-dimethylhydantoin 000118-52-5 20.0-30.0 No Boric acid 010043-35-3 10.0-20.0 Yes CoC List 1,3-Dichloro-5-ethyl-5-methylhydantoin 089415-87-2 7.0-15.0 No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).1-Bromo-3-chloro-5,5-dimethylhydantoin 016079-88-2 240-230-0 40.0-60.0 -------- ------- ---- No 1,3-Dichloro-5,5-dimethylhydantoin 000118-52-5 204-258-7 20.0-30.0 H317, H400, H302, H314, H272, EUH031 ------- No Boric acid 010043-35-3 233-139-2 10.0-20.0 H360 ------- Yes 1,3-Dichloro-5-ethyl-5-methylhydantoin 089415-87-2 401-570-7 7.0-15.0 H271, H331, H314, H302, H317, H400 ------- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :January 05, 2015 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3* 1 1 -
Warnings
Hazard statements
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Danger. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May damage fertility or the unborn child May intensify fire; oxidizer
Precautionary Statements
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood Use personal protective equipment as required. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace Keep away from heat/sparks/open flames/hot surfaces - No smoking Keep/Store away from clothing/ other combustible materials. Take any precaution to avoid mixing with combustibles. Keep only in original container.
Response
Immediately call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell. Immediately call a POISON CENTER or doctor/physician
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam for extinction
Absorb spillage to prevent material damage
Storage
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable.
Interactions with Other Chemicals
Reacts with other household chemicals such as acid toilet bowl cleaners, rust removers, acids, vinegar, and ammonia-containing products to produce hazardous gases, such as chlorine/bromine and other chlorinated/brominated compounds. Avoid contact with strong alkalis. -
Acute health effects
From SDS:
Hazards Identification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Danger. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May damage fertility or the unborn child May intensify fire; oxidizer
Potential Health Effects
Eye Contact: Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes.
Skin Contact: Corrosive. (based on components) Causes burns.
Inhalation: Corrosive by inhalation (based on components). Inhalation of corrosive fumes/gases may cause coughing, choking, headache, dizziness, and weakness for several hours. Pulmonary edema may occur with tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs. Pulmonary edema can be fatal. May cause irritation of respiratory tract. Harmful by inhalation.
Ingestion: Causes burns (based on components). Ingestion causes burns of the upper digestive and respiratory tract. May cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the mouth. Swelling of the throat may cause shortness of breath and choking May cause lung damage if swallowed. May be fatal if swallowed and enters airways. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May be harmful if swallowed. -
Chronic health effects
From SDS:
See Carcinogenicity. -
Carcinogenicity
No information available.
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Handling information
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Avoid dust formation. Fine dust dispersed in air may ignite. Wear personal protective equipment. Keep away from heat, sparks and open flame. No smoking. Do not breathe dust. Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials. Keep away from heat and sources of ignition. Keep in properly labeled containers. Do not store near combustible materials. Store in accordance with the particular national regulations. Store in accordance with local regulations.
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Disposal information
Dispose of in accordance with all applicable federal, state, and local regulations.
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California Prop. 65 Warning
This product does not contain any Proposition 65 chemicals.
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First Aid
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Seek immediate medical attention/advice. Remove contact lenses, if applicable, and continue flushing.
Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes If skin irritation persists, call a physician. For severe burns, immediate medical attention is required.
Inhalation: Move to fresh air. If not breathing, give artificial respiration. Administer oxygen if breathing is difficult and you are trained.
Ingestion: Do NOT induce vomiting. Rinse mouth. Clean mouth with water and afterwards drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately.
General Advice: Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.
Notes to Physician: Treat symptomatically. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause sensitization of susceptible persons.
Protection of First Responders: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
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